流体涡旋中螺旋波不稳定发展的理论研究   总被引：3，自引：0，他引：3       下载免费PDF全文

陶建军  李朝奎 《地球物理学报》2008,51(3):650-656

文章利用柱坐标下的流体涡度方程,通过求初始时刻的解析解,研究了螺旋波的不稳定发展问题.结论是：涡旋中螺旋波动之间可以通过基本流耦合相互作用,出现共振不稳定增长.其增长率大小与初始扰动的波数相关,数值计算结果也表明：波动在发展过程中,螺旋带状结构将越来越明显,螺旋角越来越小.  相似文献   

A sensitivity analysis of Hortonian flow   总被引：6，自引：0，他引：6  

J.-O. Delfs  C.-H. Park  O. Kolditz   《Advances in water resources》2009,32(9):1386-1395

We present a sensitivity analysis for infiltration excess (Hortonian) overland flow based on a classic laboratory experiment by Smith and Woolhiser [Smith RE, Woolhiser DA. Overland flow on an infiltrating surface. Water Resour Res 1971;7(4):899–913]. The model components of the compartment approach are comprised of a diffusive wave approximation to the Saint–Venant equations for overland flow, a Richards model for flow in the variably saturated zone, and an interface coupling concept that combines the two components. In the coupling scheme a hydraulic interface is introduced to allow the definition of an exchange flux between the surface and the unsaturated zone. The effects of friction processes, soil capillarity, hydraulic interface, and vertical soil discretization on both infiltration and runoff prediction are investigated in detail. The corresponding sensitivity analysis is conducted using a small-perturbation method. As a result the importance of the hydraulic processes and related parameters are evaluated for the coupled hydrosystem.  相似文献   

多接收电感耦合等离子体质谱Cu同位素测定中的干扰评估   总被引：15，自引：1，他引：14  

蔡俊军  朱祥坤  唐索寒  李世珍  何学贤 《高校地质学报》2006,12(3):392-397

多接收电感耦合等离子体质谱（MC—ICP—MS）是高精度测定铜同位素的新方法,然而在测定中也可能存在干扰。为此对MC—ICPMS Cu同位素测定中的可能干扰进行了评估。主要包括以下方面的内容：（1）对所用标准物质和试剂进行了纯化,所用标准物质和试剂对Cu同位素的同质异位素干扰可以忽略;（2）运用K和／参数进行了讨论,其中K为样品中的Cu浓度与标准溶液中Cu浓度的比值,f为在一定Cu浓度的标准溶液中干扰信号相对于^63Cu真实信号的比值。理论模拟表明,当K值小于1时,即使在质量为63处的干扰很小,对ε^65 Cu的影响也可能很大;（3）通过对理论模拟结果与实际测定结果的对比,发现对所用的试剂而言质量数为65的干扰可以忽略不计;（4）实际测定结果表明,当样品中Cu的浓度是标样中Cu的浓度的0．5～4倍时,测试获得的样品的ε^65值与其真值在误差范围内一致;（5）对潜在的基质效应重点研究了Fe和Co对Cu同位素测定的影响。实验结果表明,当Fe／Cu〈100,Co／Cu〈7时,Fe,Co不影响Cu同位素比值的测定;（6）10个月的重现性研究结果为ε^65=3．5±1．0（2SD）。该测定值在误差范围内与文献报道的值一致  相似文献   

The interannual variability of East Asian Monsoon and its relationship with SST in a coupled Atmosphere-Ocean-Land climate model   总被引：5，自引：1，他引：4  

Wang Huijun 《大气科学进展》2000,17(1):31-47

1.IntroductionThelargestinterannualvariabilityassociatedwiththeENSOcycleexistsinmonsoonregionsliketheAfricanmonsoon,Australianmonsoon,Pan--AmericanmonsoonandAsianmonsoon(RopelewskiandHalpert,1987;WebsterandYang,1992;JuandSlingo,1995).OnebasicquestionishowtorepresenttheAsianmonsoonanditsvariability.WebsterandYang(1992)foundareasonableindexbyaveragingthezonalwindshearbetween850hpaand200hpaovertheSouthAsianregion(40--110E,0--20N)todescribetheSouthAsianmonsooncirculationanditsvariability.…  相似文献   

Dynamic soil–structure interaction analysis via coupled finite-element–boundary-element method     

M. Yazdchi  N. Khalili  S. Valliappan 《Soil Dynamics and Earthquake Engineering》1999,18(7):502

In this paper, a study on the transient response of an elastic structure embedded in a homogeneous, isotropic and linearly elastic half-plane is presented. Transient dynamic and seismic forces are considered in the analysis. The numerical method employed is the coupled Finite-Element–Boundary-Element technique (FE–BE). The finite element method (FEM) is used for discretization of the near field and the boundary element method (BEM) is employed to model the semi-infinite far field. These two methods are coupled through equilibrium and compatibility conditions at the soil–structure interface. Effects of non-zero initial conditions due to the pre-dynamic loads and/or self-weight of the structure are included in the transient boundary element formulation. Hence, it is possible to analyse practical cases (such as dam–foundation systems) involving initial conditions due to the pre-seismic loads such as water pressure and self-weight of the dam. As an application of the proposed formulation, a gravity dam has been analysed and the results for different foundation stiffness are presented. The results of the analysis indicate the importance of including the foundation stiffness and thus the dam–foundation interaction.  相似文献   

Characterisation of Fulvic Acids and Glycyrrhizic Acid by Time‐of‐Flight Secondary Ion Mass Spectrometry     

Wilfried Szymczak  Manfred Wolf  Klaus Wittmaack 《洁净——土壤、空气、水》2001,28(7):350-358

Fulvic acids of different origin, spray deposited on polished silicon after dissolution in high‐purity water without any additives, were analysed by time‐of‐flight secondary ion mass spectrometry (TOF‐SIMS) in combination with oblique 24...36 keV SF₅⁺ ion bombardment. The observed, highly reproducible mass spectra cover more than five orders of magnitude in dynamic range, without background subtraction. Apart from lines due to atomic ions and low‐mass ion fragments, the mass spectra exhibit broad maxima between m/z 200...350, mainly due to a beat‐like superposition of lines at every single mass number, up to at least m/z 400. In the negative ion spectra the beats have a spacing of m/z 14, corresponding to a CH₂‐unit. The high‐mass tails of the spectra extend well beyond m/z 5000, with similar slopes in the positive and the negative ion mass spectra. The negative spectra appear to be less affected by fragmentation products than the positive spectra. Fulvic acids (FAs) of different origin show distinctly different spectra, with mean masses ranging between m/z ≈ 450 and 580 (for a low‐mass cut‐off m/z 150). To further verify the ability of TOF‐SIMS to detect molecules and clusters with masses significantly above the maxima of the FA spectra, samples of glycyrrhizic acid (GA, as GA ammonium salt with molecular weight 840) were also analysed. Parent ions as well as multimers (GA)_n were observed as positive and negative ions, up to n = 4 (m/z 3320). The results are compared with spectra recently obtained by other mass spectrometric techniques.  相似文献   

太湖、洞庭湖野生青虾肌肉中有机氯农药的气相色谱-质谱法测定   总被引：4，自引：0，他引：4  

史双昕  卢婉云  邵丁丁  周丽  张烃  黄业茹 《湖泊科学》2009,21(5):631-636

使用气相色谱质谱技术测定了青虾肌肉组织中的8种有机氯农药.包括六氯苯、氯丹、滴滴涕(ΣDDTs)、艾氏剂、狄氏剂、异狄氏剂、七氯和灭蚁灵,对太湖和洞庭湖15个点位29组野士青虾样品的测定结果显示,青虾肌肉组织内残留的有机氯农药主要是六氯苯和滴滴涕,六氯苯含量为nd-13.2μg/kg(湿重),滴滴涕含量为0.790-5.82μg/kg(湿重),洞庭湖青虾肌肉中有机氯农药的含量略高于太湖青虾,两湖青虾肌肉残留有机氯农药在枯水期时的含量多数大于丰水期时的含量.  相似文献   

Untersuchungen zum Abbau von Pharmaka in kommunalen Kläranlagen mit HPLC-Electrospray-Massenspektrometrie     

E. Mhle  C. Kempter  A. Kern  J. W. Metzger 《洁净——土壤、空气、水》1999,27(6):430-436

Examination of the Degradation of Drugs in Municipal Sewage Plants Using Liquid Chromatography-Electrospray Mass Spectrometry Numerous drugs can be identified in the secondary effluent of municipal sewage plants. In order to obtain information about the degree of elimination (adsorption, aerobic degradation) of these compounds, a batch reactor containing different drugs in environmentally relevant concentrations and a suspension of activated sludge was coupled to a HPLC-MS-MS system. During a testing period of three days concentration-time-curves were recorded. For most of the examined drugs (acetamidoantipyrine, crotamiton, diclofenac, primidone, propyphenazone) solely a strong decrease of the initial concentration within the first 15 minutes was observed, which was interpreted primarily as adsorption to the activated sludge. For acetaminophenol and pentoxifyllin an additional slower decrease in concentration within several hours was observed. This slower elimination was interpreted to be caused mainly by primary degradation. It could be shown that dihydrocodeine is oxidized to hydrocodone in the batch reactor. The conjugate acetaminophen glucuronide was cleaved.  相似文献   

Occurrence and Distribution of Organic Contaminants in the Aquatic System in Berlin. Part III: Determination of Synthetic Musks in Berlin Surface Water Applying Solid-phase Microextraction (SPME) and Gas Chromatography-Mass Spectrometry (GC-MS)     

Th. Heberer  S. Gramer  H.-J. Stan 《洁净——土壤、空气、水》1999,27(3):150-156

Polycyclic musks and nitro musks were found as environmental pollutants in screening analyses of 30 representative surface water samples collected from rivers, lakes, and canals in Berlin. These synthetic musks, which are used as fragrances in cosmetics, detergents, and other products, are discharged by the municipal sewage treatment plants into Berlinπs surface waters. In particular, the polycyclic musks 1,3,4,6,7,8-hexahydro-4,6,6,7,8,8-hexamethylcyclopenta-(g)-2-benzopyrane (HHCB; Galaxolide®, Abbalide®) and 7-acetyl-1,1,3,4,4,6-hexamethyltetraline (AHTN; Tonalide®, Fixolide®) were found in the receiving surface waters at considerable concentrations up to the μg/L-level. In the Wuhle, a small brook almost totally consisting of sewage effluents, maximum concentrations were 12.5 μg/L for HHCB and 6.8 μg/L for AHTN. Additionally, the polycyclic musk 4-acetyl-1,1-dimethyl-6-tert-butylindane (ADBI; Celestolide®, Crysolide®) and 1-tert-butyl-3,5-dimethyl-2,6-dinitro-4-acetylbenzene (musk ketone) were detected at low concentrations in most of the samples. Two other nitro musks, namely 1,1,3,3,5-pentamethyl-4,6-dinitroindene (musk moskene) and 1-tert-butyl-3,5-dimethyl-2,4,6-trinitrobenzene (musk xylene), were only detected in a single surface water sample. Solid-phase microextraction (SPME) with detection by gas chromatography-mass spectrometry (GC-MS) has proven to be a rapid and reliable tool for the screening of synthetic musks in surface and sewage water samples. Internal calibration with a suitable internal standard enables reproducible quantitation of the analytes down to the low ng/L-level.  相似文献   

Occurrence and Distribution of Organic Contaminants in the Aquatic System in Berlin.Part II: Substituted Phenols in Berlin Surface Water     

K. Schmidt-Bumler  Th. Heberer  H.-J. Stan 《洁净——土壤、空气、水》1999,27(3):143-149

In a surface water screening, 30 representative surface water samples collected from rivers, canals, and lakes in Berlin were investigated for the presence of 22 substituted phenols. The phenols selected include the 11 phenols considered as “priority pollutants” by the US Environmental Protection Agency (US-EPA). Surface water samples were extracted applying solid-phase extraction with styrenedivinylbenzene adsorbent. The recoveries, determined in spiking experiments, were between 80 % and 103 %. After derivatization with N-(tert-butyldimethylsilyl)-N-methyl-trifluoroacetamide (MTBSTFA) the samples were analyzed by capillary gas chromatography-mass spectrometry (GC-MS). Phenol, cresols, 2-ethylphenol, 2-chlorophenol, 4-chloro-3-methylphenol, pentachlorophenol, 2-nitrophenol, and 4-nitrophenol were detected in the surface water samples at concentrations between 0.02 μg/L and 7.8 μg/L, respectively. The distribution of these residues in the Berlin surface waters showed that the phenolic residues, with the exception of pentachlorophenol and 2-ethylphenol, do not originate primarily from municipal sewage treatment plants discharges. Some of the phenols are formed naturally or occur as ubiquitous anthropogenic contaminants in the aquatic system.  相似文献